American Institute of Chemical Engineers
Nuclear Engineering Division

AIChE 2005 Annual Meeting

Nuclear Engineering Division Program Sessions

Click on the links below to view the various session abstracts and slides.  For each session content table click on the Session Number to view the abstract and the Presentation Title to view the presentation.

#155 - Advances in Separations and Immobilization of Nuclear Waste (14001)

#210 - Developments in Thermochemical and Electrolytic Routes to Hydrogen Production: Part I (14006)

#258 - Developments in Thermochemical and Electrolytic Routes to Hydrogen Production: Part II (14008)

#348 - Developments in Thermochemical and Electrolytic Routes to Hydrogen Production: Part III (14009)

#301 - Application of Computer Modeling in the Nuclear Industry (14003)

#405 - High Temperature Systems and Materials for Hydrogen Production: Part I (14004)

#502 - High Temperature Systems and Materials for Hydrogen Production: Part II (14000)

#480 - The Flammable Gas Hazard and Advances in Actinide and High Level Waste Processes (14005)

#538 - Chemical Engineering Advances in the Nuclear Fuel Cycle (14002)

#581 - Nuclear Hydrogen Production Process Design and Economics (14007)

#155 - Advances in Separations and Immobilization of Nuclear Waste (14001)

The goal of this venue is to present basic and applied research contributions in the areas of DOE waste pretreatment and immobilization. Papers that further the current understanding of baseline technologies that are planned to be implemented or have been implemented are solicited. Sessions topics will include, but are not limited to the following: evaporation, filtration, precipitation, solvent extraction, ion exchange, slurry handling, vitrification, bulk vitrification, Pu Immobilization, steam reforming, and waste form development. Contributions that present process improvements to existing treatment plants are welcome. Experimental contributions that benchmark the performance of commercially available ion exchange resins that have not been selected for use by the DOE research and development programs are encouraged. Papers that discuss the advances in the supplemental treatment of Hanford wastes are highly encouraged. Papers that present advancements in waste form development (e.g. increase waste loading), are also encouraged.

  Foaming and Antifoaming in Radioactive Waste Pretreatment and Immobilization Processes
Darsh T. Wasan, Alex D. Nikolov, Krishna Vijayaraghavan, D. P. Lambert, T. Bond Calloway, Michael Stone
  Gas and Oil Retention in Waste Slurries: Role of Particle Interactions
Alex D. Nikolov, Darsh T. Wasan, Michael Stone, T. Bond Calloway, D. P. Lambert
  Fractional Crystallization of Sodium Salts from Low- and Medium-Curie Wastes
Hatem Alsyouri, George Dumont, Laurent Nassif, Ronald W. Rousseau
  Copper Catalyzed Peroxide Oxidation Testing for Tetraphenylborate Decomposition in Srs Tank 48h
D. P. Lambert, Sam D. Fink, Thomas B. Peters
  Optimization of Ultrafilter Feed Conditions for Hlw Filtration Using Classical Filtration Models
John Geeting, Rich Hallen, Reid Peterson

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#210 - Developments in Thermochemical and Electrolytic Routes to Hydrogen Production: Part I (14006)

This symposium focuses on nontraditional methods for generating hydrogen that would reduce reliance on fossil fuels, in particular those that use heat from a nuclear power plant to dissociate water into hydrogen and oxygen by thermochemical or electrolytic means. This session focuses on assessment of thermochemical hydrogen production methods and the most novel hydrogen production processes.

  Hythec: Aims and First Assessments of an Ec Funded Project on Massive Scale Hydrogen Production Via Thermochemical Cycles
Ray W. K. Allen, Bruce C. R. Ewan, Geoff H. Priestman, Rachael Elder, Alain Le Duigou, Jean-Marc Borgard, Bruno Larousse, Denis Doizi, C. Eysseric, Giovanni Cerri, Giovanni de Maria, Coriolano Salvini, Ambra Giovannelli, Martin Roeb, Nathalie Monnerie, Mark Schmitz, Christian Sattler, Arturo Buenaventura, Stephane Dechelotte, Olivier Baudouin
  A Standardized Method for Evaluating the Potential of Alternative Thermochemical Cycles
Michele Lewis, Joseph Masin
  Assessing the Efficiency Limits for Hydrogen Production by Thermochemical Cycles
Bruce C. R. Ewan, R W K Allen
  Production of H2 by Hydrolysis of Zn Aerosol Freshly Made by Evaporation and Condensation
Frank O. Ernst, Antonio Tricoli, Sotiris E. Pratsinis, Aldo Steinfeld
  Reaction Kinetics and Modeling of the Aerosol Thermal Decomposition of Zno in for Solar Thermochemical Production of H2
Christopher Perkins, Paul Lichty, Alan W. Weimer
  Radiolytic Water Splitting: Demonstration at the Pm3-a Reactor
Alfred Schneider

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#258 - Developments in Thermochemical and Electrolytic Routes to Hydrogen Production: Part II (14008)

This symposium focuses on nontraditional methods for generating hydrogen that would reduce reliance on fossil fuels, in particular those that use heat from a nuclear power plant to dissociate water into hydrogen and oxygen by thermochemical or electrolytic means. This session focuses on the research supporting the development of the sulfur-iodine cycle.

  Thermodynamic Efficiency Analysis of the S-I Process for Nuclear Hydrogen Production
John P. O'Connell, K.P. Bellezza, P. Narkpresert, Maximilian B. Gorensek, Paul M. Mathias
  Experimental Study of the Bunsen Reaction for the S-I Thermochemical Cycle
Giampaolo Caputo, Claudio Felici, Alberto Giaconia, Michela Lanchi, Raffaele Liberatore, Salvatore Sau
  Comparison of Reactive Distillation and Extractive Distillation Flowsheets for the Sulfur-Iodine Thermochemical Cycle
Lloyd C. Brown, Gottfried E. Besenbruch, Benjamin E. Russ, Robert T. Buckingham
  Activity and Stability of Sulfuric Acid Decomposition Catalysts for Thermochemical Water Splitting Cycles
Daniel M. Ginosar, Lucia M Petkovic, Kyle C Burch
  Applicability of Inorganic Membranes for the Production of Hydrogen Using Nuclear Energy
Brian L. Bischoff, Dane F. Wilson, Lawrence E. Powell, K. Dale Adcock
  Use of Membranes and Reactive Distillation for the Separation of Hix in the Sulphur-Iodine Cycle
Rachael H. Elder, Jean Marc Borgard, Geof H. Priestman, Bruce C. Ewan, Ray W. K. Allen
  Stability and Performance of Nafion-117 Membranes for the Concentration of Hi/Water and Hi/Water/Iodine Mixtures
Frederick F. Stewart, Christopher J. Orme

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#348 - Developments in Thermochemical and Electrolytic Routes to Hydrogen Production: Part III (14009)

This symposium focuses on nontraditional methods for generating hydrogen that would reduce reliance on fossil fuels, in particular those that use heat from a nuclear power plant to dissociate water into hydrogen and oxygen by thermochemical or electrolytic means. This session focuses on electrolytic and thermochemical-electrolytic hybrid hydrogen production processes.

  Engineering Process Model for High-Temperature Steam Electrolysis System Performance Evaluation
Carl M. Stoots, James E. O'Brien, Michael G. McKellar, Grant L. Hawkes, J. Stephen Herring
  Materials Development for Improved Efficiency of Hydrogen Production by Steam Electrolysis and Thermochemical-Electrochemical Processes
Jennifer R. Mawdsley, Deborah J. Myers, Bilge Yildiz
  Conceptual Design and Projected Performance for a Hybrid Sulfur Process
Maximilian B. Gorensek, William A. Summers, Melvin R. Buckner, Zafar H. Qureshi
  Electrochemical Generation of Hydrogen Via Gas Phase Oxidation of Sulfur DI Oxide and Hydrogen Bromide
John W. Weidner, PremKumar Sivasubramanian, Charles E. Holland, Francisco J. Freire
  Hydrolysis of Calcium Bromide: Immobilization of the Reactant on a High Surface Area Support
Vivek P. Utgikar, J. Paul Scott, Michael F. Simpson
  An Assessment of the Efficiency of the Hybrid Copper-Chloride Thermochemical Cycle
Michele Lewis, Joseph Masin

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#301 - Application of Computer Modeling in the Nuclear Industry (14003)

This session will entertain papers from the improved safe operation of reactors through the entire nuclear system clear to the transport of radionuclides in the repository and near surface environments.

  Simulations of Spouted Beds for Coating Triso Fuel Particles
Sreekanth Pannala, Dhanunjay Boyalakuntla, Charles E. A. Finney, James H. Miller, Richard A. Lowden, C. Stuart Daw
  Modeling Hanford-Rpp Treated Law Feed Evaporation
Gene Daniel
  Molecular Modeling of Crystalline Silicotitanate and Polyoxoniobate Ion Exchangers
James P. Larentzos, Edward J. Maginn
  Modeling Offgas Systems for the Hanford Waste Treatment Plant
Frank G. Smith III

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#405 - High Temperature Systems and Materials for Hydrogen Production: Part I (14004)

This session addresses high temperature systems and materials for hydrogen production.

  Progress in High Temperature Materials and Systems in the U.S. Doe Nuclear Hydrogen Initiative
Steven Randall Sherman
  Characterization of Candidate Ceramic Materials for the High Temperature Sulfuric Acid Loop in the Si Process
Merrill A. Wilson, Charles Lewinsohn
  Application of Conjugate Heat Transfer and Flow Analyses for Design Optimization of the Si Decomposer
Valery I. Ponyavin
  Evaluation of Candidate Salts for Use as High Temperature Heat Transfer Agents
David F. Williams
  Inhibiting Corrosion by Molten Fluoride Salts: Investigations on Flinak
Blandine F. Laurenty, Grant Fukuda, Darwin D. Damba, Per F. Peterson
  Recent Advances in Redox-Based Corrosion Control in Molten Salts Suitable for Use in High Temperature Heat Transfer
Michael Simpson, Galen Smolik, John P. Sharpe, David Petti, Robert Anderl

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#502 - High Temperature Systems and Materials for Hydrogen Production: Part II (14000)

Continuation of I

  Commercial Alloys for Sulfuric Acid Vaporization in Thermochemical Hydrogen Cycles
Thomas M. Lillo, Karen M. Delezene-Briggs
  Characterization of Structural Materials for Nuclear Hydrogen Generation
Ancila Kaiparambil, Radhakrishnan Santhanakrishnan, Ajit Roy, Bunsen Wong
  Durability Analyses of a Silicon Carbide Based Decomposer for the Si Process
Merrill A. Wilson
  Tensile Properties and Corrosion Susceptibility of Alloy C - 276 in S - I Environment
Ajit Roy, Joydeep Pal
  Use of Alloy 800h as a Heat-Exchanger Structural Material
Ajit Roy, Vinay Virupaksha
  Microscopic Characterization of Discontinuous Precipitation in a Nickel Aluminide Intermetallic Material
Pankaj Kumar, Ranjit K. Ray, Ajit Roy

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#480 - The Flammable Gas Hazard and Advances in Actinide and High Level Waste Processes (14005)

This session addresses the flammable gas hazard and advances in actinide and high level waste processes.

  Development of a Liquid Jet Sludge Re-Suspension Model (Used on Pulse Jets or Jet Ballasts)
George A.H. McArthur, Tim P. Tinsley, Donna McKendrick
  Impact of Alkali Source on Vitrification of Srs High Level Waste
Michael Stone, David K. Peeler, Daniel P. Lambert, Donald H. Miller, Michael E. Smith
  Determination of Bubble Size Distribution in an Oxide Reduction Electrochemical Cell
Supathorn Phongikaroon, Steven Herrmann, Shelly Li, Michael F. Simpson
  Heat Transfer from Condensate Droplets Falling through an Immiscible Layer of Tributyl Phosphate
James Laurinat
  238pu Anion Exchange Column Safety during Flow Interruptions
Edward Kyser III, James Laurinat

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#538 - Chemical Engineering Advances in the Nuclear Fuel Cycle (14002)

This session addresses chemical engineering advances in the nuclear fuel cycle. Presentations describing advances in the separations and primary waste treatment processes associated with processing irradiated nuclear fuel are encouraged. Flowsheets and process technologies promoting nuclear non-proliferation are especially encouraged.

  Ionic Liquids in Actinide and Fission Product Separations: Progress and Prospects
Mark L. Dietz, Dominique C. Stepinski, Mark P. Jensen, Paul G. Rickert, David J. Rausch
  Reprocessing Spent Nuclear Fuel Using Environmentally Sustainable Solvents
Chien M. Wai
  Redox-Active Ligands Designed to Promote Am Separation from CM and Lanthanide Fission Products in Spent Nuclear Fuel
Paul B. Duval, Eric M. Weis
  Lab-Scale Demonstration of the Urex+1 Process Using Spent Nuclear Fuel
Candido Pereira, G. F. Vandegrift, M. C. Regalbuto, A. Bakel, D. L. Bowers
  Entrainment of Aqueous Hazes in Liquid-Liquid Extraction Equipment and Their Effect on Fission Product Carry-over in Fuel Processing Operations
Stuart Arm

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#581 - Nuclear Hydrogen Production Process Design and Economics (14007)

Hydrogen can be produced via water-splitting by the use of heat from a high-temperature nuclear reactor combined with various hydrogen production processes, including thermochemical, electrolytic, and hybrid cycles. This session will include papers discussing the plant design, system analysis, economics and infrastructure issues of nuclear hydrogen production. Analysis of plant efficiency and process modeling of hydrogen production processes (with emphasis on overall plant system performance) may also be included.

  Nuclear Hydrogen for Production of Liquid Hydrocarbon Transport Fuels
Charles Forsberg
  Hydrogen Costs for the Pbmr Thermal Reactor and the Westinghouse Process
Edward J. Lahoda, Willem Kriel, Michael M. Nigra, Garrett T. McLaughlin
  Development of Design and Simulation Model and Safety Study of Large-Scale Hydrogen Production Using Nuclear Power
Sal B. Rodríguez Jr., Randall O. Gauntt, Shripad T. Revankar, Karen Vierow
  Generation of Hydrogen Using Electrolyzer with Sulfur Dioxide Depolarized Anode
John L. Steimke, Timothy J. Steeper
  Economic Analysis of Hydrogen Production Via Water-Splitting Using Nuclear Energy
William A. Summers, Maximilian B. Gorensek
  Simulation of Decomposition of Sulfur Trioxide Gas on Self-Catalytic Metallic Material
Kiran Kumar Muramalla, Yitung Chen, Anthony E. Hechanova

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